Baharuddin Hamzah, Irwan Said, Ririen Hardani


The influence of chromium(III) ion on copper(II) ion extraction using kerosene emulsion with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (HPMBP) as a cation carrier was investigated. The optimum condition for copper(II) extraction were as follows: concentration of mixed surfactant (span 80+span 20) was 5%, volume ratio of kerosene and internal phase was 1, concentration of HPMBP was 0.025 M, concentration of HCl was 1 M, volume ratio of emulsion and external phase was 0.143. The results showed that the extraction of copper(II) ion was selective to chromium(III) ion, relatively. The result also showed that the presence of 500 ppm chromium(III) ion decrease the percentage of copper(II) ion extraction from 98.6 to 91.0.


HPMBP, kerosene emulsion, copper(II) ion, chromium(III) ion, extraction


Basualto, C., Poblete, M., Marchese, J., Ochoa, A., Acosta, A., Sapag, J., & Valenzuela, F. (2006). Extraction of cadmium from aqueous solutions by emulsion liquid membranes using a stirred transfer cell contactor, Journal of the Brazilian Chemical Society, 17(7).

Bourenane, S., Samar, M. E. H., & Abbaci, A. (2003). Extraction of cobalt and lead from waste water using a liquid surfactant membrane emulsion. Acta Chimica Slovenika., 50, 663–675.

Chakravarti, A. K., Chowdhury, S. B., & Mukherjee, D. C. (2000). Liquid membrane multiple emulsion process of separation of copper(II) from waste waters. Colloids and Surfaces, A Physiochemical and Engineering Aspects, 166(1–3), 7–25.

Gan, S. (1980). Farmakologi dan terapi, Bagian Farmakologi Fakultas Kedokteran. Jakarta: Universitas Indonesia.

Gawronski, R. & Religa, P. (2007). Transport mechanism of chromium(III) through the unmixed bulk liquid membrane containing dinonylnaphthalenesul phonic acid as a carrier. Journal of Membrane Science, 289(1-2), 187–190.

Hamzah, B. (2010). Aplikasi 1-fenil-3-metil-4- bnezoil-5-pirazolon sebagai pembawa kation pada ekstraksi ion tembaga(II) menggunakan teknik emulsi membrane cair, Disertasi, Universitas Hasanuddin, Makassar.

Hamzah, B. & Said, I. (2006). Sintesis beberapa senyawa kelat turunan pirazolon dan aplikasinya pada ekstraksi ion logam dari larutan. Palu: Lembaga Penelitian Universitas Tadulako.

Hamzah, B. (2001). Determination of the extraction constant in cadmium extraction with HPMBP. Prosiding Seminar Nasional Kimia Palu, 22-25.

Hamzah, B., & Pulukadang, S.V. (1999). Sintesis 1-fenil-3-metil-4-benzoil-5-pirazolon dan aplikasinya pada ekstraksi logam berat dalam larutan. Lemlit Universitas Tadulako.

Ivanova, E. (1987). 1-phenyl-3-methyl-4- benzoyl-5-pyrazolone as extraction reagent for Cu, Zn, Ni, Co, Mn and Fe in AAS. Analytical Chemistry., 288(62).

Jia, J-M., Fu, L. & Yude, C. (1988). Synthesis of pyrazolone and extraction of metal ion. Journal of Radioanalytichal and Nuclear Chemistry., 131, 54-63.

Kozlowski, C., Apostoluk, W., Walkowiak, W., & Kita, A. (2002). Removal of Cr(VI), Zn(II) and Cd(II) ions by transport across polymer inclusion membranes with basic ion carriers. Physiochemical Problems of Mineral Processing, 36, 115–122.

Kozlowski, C., & Walkowiak, W. (2005). Applicability of liquid membranes in chromium transport with amines as ion carriers. Journal of membrane science, 266(1–2), 143–150.

Kumaresan, T., Begum, K. M. M. S., Sivashanmugam, P., Anantharaman, N., & Sundaram, S. (2003). Experimental studies on treatment of distillery effluent by liquid membrane extraction. Chemical Engineering Journal., 95, 199–204.

Luan, J., & Plaisicr, A. (2004). Study on treatment of wastewater containing nitrophenol compounds by liquid membrane process. Journal of Membrane Science, 229, 235-239.

Manea, F., Dalea, V., Masu, S., & Negrea, P. (2003). Separation of Co(II) and Ni(II) ions from wastewater by emulsion liquid membrane technique. Diunduh kembali dari content/pdf/385.pdf.

Mitiche, L., Tingry. S., Seta, P. & Sohmoune, A. (2008). Facilitated transport of copper(II) across supported liquid membrane and polymeric plasticised membrane containing 3-phenyl-4-benzoylisoxazol -5-on as carrier. Journal of Membrane Science, 25(2), 605-611.

Park, W., Kim, G. W., Kim, S. S. & Sohn, I.J. (2001). Facilitated transport of Cr(VI) through a supported liquid membrane with trioctylmethyl ammonium chloride as a carrier. Sep.Sci.Tech, 36(10), 2309–2326.

Park, Y., Skelland, A. H. P., Forney, L. J., & Kim, J. H. (2006). Removal of phenol and substituted phenols by newly developed emulsion liquid membrane process. Water Research, 40, 1763-1772.

Sabry, R., Hafez, A., Khedr, M., & Hassanin, A.E. (2007). Removal of lead by an emulsion liquid membrane. Desalination, 212(1–3), 165–175.

Saleh, M.I., Ahmad, M., & Darus, H. (1990). Solvent extraction of lanthanum(III), europium(III), and lutetium(III) with fluorinated 1-phenyl-3-methyl-4-benzoyl- 5-pyrazolone into chloroform. Talanta, 37, 757-759.

Saravanan, S., Begum, K. M. M. S., & Anantharaman, N. (2006). Removal of hexavalent chromium by emulsion liquid membrane technique. Journal of the University of Chemical Technology and Metallurgy, 41(3), 333–342.

Sengupta, B., Sengupta, R., & Subrahmanyam, N. (2006). Copper extraction into emulsion liquid membranes using LIX 984N-C, Hydrometallurgy, 81(1), 67–73.

Sukardjo. (1985). Kimia koordinasi (Ed. 1st). Jakarta: Bina Aksara.

Valenzuela, F., Araneda, C., Vargas, F., Basualto, C., & Sapag, J. (2009). Liquid membrane emulsion process for recovery the copper content of a mine drainage. Chemical Engineering Research and Design, 87(1), 102-108.

Wang, S., He, P., Hao, D., & Zhu, Y. (2002). Treatment of Zn-containing acidic waste water by emulsion liquid membrane process. Diunduh kembali dari

Yang, L., Zhang, Z., Guo, Y., Gao, X., & Takeuchi, H. (2005). Uranium(VI) extraction by liquid surfactant membrane with N-alkylcapro lactams as a carrier. Separation and Purification Technology, 47, 88-94.

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